Stefanos Tsitsipas saved 11 of 12 break points defeating Roger Federer in an hour and 36 minutes.
"It's a great moment not just for me, for my country, my team," Tsitsipas, the lone top-10 player in Greek history, told reporters. "I'm proud of myself, how hard I fought today, how concentrated I stayed in the break points.
Awaiting him on Monday (AEST) is Dominic Thiem, who ended Zverev's repeat bid with a 7-5 6-3 win in the other match.
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