Labor leader Luke Foley says ASIO should be consulted before any deal with a foreign government to buy into the NSW electricity network.
Mr Foley has continued to attack the Baird government's plans to lease 49 per cent of poles and wires just 72 hours out from the NSW election.
The opposition leader also expressed a lack of faith in the Foreign Investment Review Board over the sale of electricity assets.
Treasurer Andrew Constance has said he met with representatives from a Chinese government-owned company with The China Daily reporting a meeting about the sale of the network.
"I don't think it's a smart thing to do to sell our electricity network to a foreign government," Mr Foley said in the marginal electorate of Swansea on the NSW Central Coast.
"Transgrid ... powers Parliament House. The distribution network goes to Holsworthy Army base, to the Richmond RAAF base, to our defence installations.
"Of course the security agencies (including ASIO, ASIS) will have some views on these matters."
Mr Foley said the FIRB had ticked off on the China State Grid Corp buying into the electricity network in other states.
But said his concern wasn't because the company was Chinese - just that it was not Australian.
"Transgrid sends power into Parliament House in Canberra ... And the thing about high voltage transmission lines is that you can transport data on high voltage lines," he said.
"So whoever owns the transmission business will have an extraordinary capacity into the future.
"I don't see the Foreign Investment Review Board as sufficient protection for the people of NSW."
He said reports Mr Baird had attended a function with the president of China State Grid Corporation meant he couldn't be trusted.
Mr Baird has denied the suggestion, made by federal Labor senator Sam Dastyari.
"I don't trust him," Mr Foley said of Mr Baird.
"He hasn't been open and up front with the people of this state about what he's been up to."
Mr Foley was speaking outside the Vales Point power station, which the NSW government failed to sell last year.
Swansea is a marginal Liberal seat held by 0.3 per cent, after the incumbent Garry Edwards was disendorsed after he was dragged into the ICAC developer donations inquiry.
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