"The Everton defender picked up an injury in training on Friday morning and will return to his club for treatment," the FA said in a statement.
Roy Hodgson's side play a Euro 2016 qualifier against Slovenia at Wembley on Saturday before facing old rivals Scotland in a friendly at Celtic Park on Tuesday.
The FA said no further call-ups would be made at this time.
(Reporting by Toby Davis; editing by Ken Ferris)
