It means the Argentinian faces the prospect of arriving at Wimbledon without any grasscourt matches under his belt.
Queen's, which features world number one and Wimbledon champion Andy Murray and world number three Stan Wawrinka, has also lost French Open champion Rafa Nadal after he withdrew to recover after his triumph at Roland Garros.
Australian Thanasi Kokkinakis and Briton James Ward have been awarded main draw wildcards.
(Reporting by Martyn Herman; editing by Mark Heinrich)
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