The win means South Korea have made it out of the group stage at the World Cup for the first time. They were eliminated at the first hurdle in their only other appearance in 2003.
The Asian side, who started the day in bottom place, fell behind in the first half but tied the game in the 53rd minute when Cho So-hyun planted a header into the net from close range.
Veronica Boquete opening the scoring for Spain in the 29th minute, neatly converting a left-wing cross from 12 yards out.
(Reporting by David Ljunggren. Editing by Andrew Both)
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