Analysts predict talks between Julia Gillard and President Sein will focus on aid and the economy, but activists are hoping issues of human rights will be put first.
Bawk Nan N'Pawt has lived in Sydney for 18 years and says President Sein's visit brings back old and bitter memories. Her 22-year old daughter is organising a protest for the President's visit.
Roi Ja Lahpai says she wants Julia Gillard to know that: "[President Sein] does tell a lot of lies, we can't believe everything he says and his administration."
Since taking power in 2011 the former military commander has overseen major reform in Burma like freeing political prisoners, relaxing media control and allowing the re-emergence of Aung San Suu Kyi's party in 2012.
But Director of Burma Office, Dr Myint Cho, says there are still few changes on the ground.
"The people suffer a lot of hardships," he said.
"I call on the Prime Minister Julia Gillard to raise human rights issue during the meeting with Thein Sein."
President Sein was previously banned from obtaining a visa to Australia but sanctions, including financial ones, have since been lifted.
He will be formally welcomed by Governor General Quentin Bryce at Government House.
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