Two sets up and at 1-1 in the third, Wimbledon champion Murray suffered a huge lapse, allowing the 267th-ranked Frenchman to charge out to a 5-1 lead under the lights at Rod Laver Arena.
Briton Murray simply flicked a switch and won 23 consecutive points in a blistering finish to seal the match with a big serve.
The fourth seeded Scot will play Feliciano Lopez for a place in the fourth round.
(Reporting by Ian Ransom; Editing by Justin Palmer)
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