Neymar was transferred from Barcelona this month after PSG triggered his 222-million-euro (201.6 million pounds) release clause.
PSG tweeted a picture of Neymar's shirt and shorts from the dressing room, saying "Everything is in place #neymarJrpremiere".
Neymar was not allowed to play at home against Amiens last weekend because the French federation had not received his transfer certificate from their Spanish counterparts.
(Reporting by Julien Pretot; Editing by Clare Fallon)
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