Robinho was part of the Brazil side that exited the recent Copa America tournament following a quarter-final penalty shootout defeat by Paraguay.
He will join the four-times reigning Chinese champions, who appointed 2002 World Cup winning coach Scolari last month after sacking Italian Fabio Cannavaro after less than half a season in charge.
Scolari has been quick to make changes and signed Brazilian midfielder Paulinho from English outfit Tottenham Hotspur recently for a reported fee of around $15 million.
Guangzhou, the 2013 AFC Champions League winners, are not the only Chinese club to have spent money on expensive internationals with Shanghai Shenhua also paying $14.5 million to Turkish side Besiktas for Senegal international Demba Ba.
(Writing by Sudipto Ganguly in Mumbai; Editing by John O'Brien)
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